No. Charging Fire doesn't stack with Greater Mobile Attack, either. The problem isn't that Charging Fire and Ambush don't stack, it's that Double/Triple Attack and Charging Fire don't stack. You replace your whole turn for Charging Fire, so you don't get your normal attack action, which is when you would use Double/Triple Attack.
_________________ "An elegant, easy-to-understand concept or mechanic that accomplishes 95% of what you want is much better than a clunky, obtuse mechanic that gets you 100%" - Rob Daviau
"You can't per aspera ad astra unless there's some aspera in front of your astra. And that means sometimes the aspera gets you." - Donald X. Vaccarino
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